15A NCAC 02D .1104. TOXIC AIR POLLUTANT GUIDELINES  


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  • A facility shall not emit any of the following toxic air pollutants in such quantities that may cause or contribute beyond the premises (adjacent property boundary) to any significant ambient air concentration that may adversely affect human health. In determining these significant ambient air concentrations, the Division shall be guided by the following list of acceptable ambient levels in milligrams per cubic meter at 77° F (25° C) and 29.92 inches (760 mm) of mercury pressure (except for asbestos):

     

     

    Pollutant (CAS Number)

     

    Annual (Carcinogens)

     

     

     

    24-hour

    (Chronic Toxicants)

     

     

    1-hour

    (Acute Systemic Toxicants)

     

    1-hour

    (Acute Irritants)

     

      acetaldehyde (75-07-0)

     

     

     

    27

      acetic acid (64-19-7)

     

     

     

    3.7

      acrolein (107-02-8)

     

     

     

    0.08

      acrylonitrile (107-13-1)

     

    0.03

    1

     

      ammonia (7664-41-7)

     

     

     

    2.7

      aniline (62-53-3)

     

     

    1

     

      arsenic and inorganic arsenic    compounds

    2.1 x 10-6

     

     

     

      asbestos (1332-21-4)

    2.8 x 10-6 fibers/ml

     

     

     

      aziridine (151-56-4)

     

    0.006

     

     

      benzene (71-43-2)

    1.2 x 10-4

     

     

     

      benzidine and salts (92-87-5)

    1.5 x 10-8

     

     

     

      benzo(a)pyrene (50-32-8)

    3.3 x 10-5

     

     

     

      benzyl chloride (100-44-7)

     

     

    0.5

     

      beryllium (7440-41-7)

    4.1 x 10-6

     

     

     

      beryllium chloride  (7787-47-5)

    4.1 x 10-6

     

     

     

      beryllium fluoride  (7787-49-7)

    4.1 x 10-6

     

     

     

      beryllium nitrate  (13597-99-4)

    4.1 x 10-6

     

     

     

      bioavailable chromate pigments, as chromium (VI) equivalent

    8.3 x 10-8

     

     

     

      bis-chloromethyl ether (542-88-1)

    3.7 x 10-7

     

     

     

      bromine (7726-95-6)

     

     

     

    0.2

      1,3-butadiene (106-99-0)

    4.4 x 10-4

     

     

     

      cadmium (7440-43-9)

    5.5 x 10-6

     

     

     

      cadmium acetate  (543-90-8)

    5.5 x 10-6

     

     

     

      cadmium bromide  (7789-42-6)

    5.5 x 10-6

     

     

     

      carbon disulfide (75-15-0)

     

    0.186

     

     

      carbon tetrachloride (56-23-5)

    6.7 x 10-3

     

     

     

      chlorine (7782-50-5)

     

    0.0375

     

    0.9

      chlorobenzene (108-90-7)

     

    2.2

     

     

      chloroform (67-66-3)

    4.3 x 10-3

     

     

     

      chloroprene (126-99-8)

     

    0.44

    3.5

     

      cresol (1319-77-3)

     

     

    2.2

     

      p-dichlorobenzene  (106-46-7)

     

     

     

    66

      dichlorodifluoromethane   (75-71-8)

     

    248

     

     

      dichlorofluoromethane  (75-43-4)

     

    0.5

     

     

      di(2-ethylhexyl)phthalate  (117-81-7)

     

    0.03

     

     

      dimethyl sulfate (77-78-1)

     

    0.003

     

     

      1,4-dioxane (123-91-1)

     

    0.56

     

     

      epichlorohydrin (106-89-8)

    8.3 x 10-2

     

     

     

      ethyl acetate (141-78-6)

     

     

    140

     

      ethylenediamine (107-15-3)

     

    0.3

    2.5

     

      ethylene dibromide  (106-93-4)

    4.0 x 10-4

     

     

     

      ethylene dichloride  (107-06-2)

    3.8 x 10-3

     

     

     

      ethylene glycol monoethyl ether

    (110-80-5)

     

    0.12

    1.9

     

      ethylene oxide (75-21-8)

    2.7 x 10-5

     

     

     

      ethyl mercaptan (75-08-1)

     

     

    0.1

     

      fluorides

     

    0.016

    0.25

     

      formaldehyde (50-00-0)

     

     

     

    0.15

       hexachlorocyclopentadiene (77-47-4)

     

    0.0006

    0.01

     

      hexachlorodibenzo-p-dioxin

    (57653-85-7)

    7.6 x 10-8

     

     

     

      n-hexane (110-54-3)

     

    1.1

     

     

      hexane isomers except n-hexane

     

     

     

    360

      hydrazine (302-01-2)

     

    0.0006

     

     

      hydrogen chloride  (7647-01-0)

     

     

     

    0.7

      hydrogen cyanide (74-90-8)

     

    0.14

    1.1

     

      hydrogen fluoride  (7664-39-3)

     

    0.03

     

    0.25

      hydrogen sulfide  (7783-06-4)

     

    0.12

     

     

      maleic anhydride  (108-31-6)

     

    0.012

    0.1

     

      manganese and compounds

     

    0.031

     

     

      manganese cyclopentadienyl tricarbonyl (12079-65-1)

     

    0.0006

     

     

      manganese tetroxide (1317-35-7)

     

    0.0062

     

     

      mercury, alkyl

     

    0.00006

     

     

      mercury, aryl and inorganic compounds

     

    0.0006

     

     

      mercury, vapor (7439-97-6)

     

    0.0006

     

     

      methyl chloroform (71-55-6)

     

    12

     

    245

      methylene chloride (75-09-2)

    2.4 x 10-2

     

    1.7

     

      methyl ethyl ketone  (78-93-3)

     

    3.7

     

    88.5

      methyl isobutyl ketone  (108-10-1)

     

    2.56

     

    30

      methyl mercaptan (74-93-1)

     

     

    0.05

     

      nickel carbonyl  (13463-39-3)

     

    0.0006

     

     

      nickel metal (7440-02-0)

     

    0.006

     

     

      nickel, soluble compounds, as nickel

     

    0.0006

     

     

      nickel subsulfide  (12035-72-2)

    2.1 x 10-6

     

     

     

      nitric acid (7697-37-2)

     

     

     

    1

      nitrobenzene (98-95-3)

     

    0.06

    0.5

     

       n-nitrosodimethylamine  (62-75-9)

    5.0 x 10-5

     

     

     

      non-specific chromium (VI) compounds, as chromium (VI) equivalent

    8.3 x 10-8

     

     

     

      pentachlorophenol  (87-86-5)

     

    0.003

    0.025

     

      perchloroethylene (127-18-4)

    1.9 x 10-1

     

     

     

      phenol (108-95-2)

     

     

    0.95

     

      phosgene (75-44-5)

     

    0.0025

     

     

      phosphine (7803-51-2)

     

     

     

    0.13

      polychlorinated biphenyls

    (1336-36-3)

    8.3 x 10-5

     

     

     

      soluble chromate compounds, as chromium (VI) equivalent

     

    6.2 x 10-4

     

     

      styrene (100-42-5)

     

     

    10.6

     

      sulfuric acid (7664-93-9)

     

    0.012

    0.1

     

      tetrachlorodibenzo-p-dioxin

    (1746-01-6)

    3.0 x 10-9

     

     

     

      1,1,1,2-tetrachloro-2,2,- difluoroethane (76-11-9)

     

    52

     

     

      1,1,2,2-tetrachloro-1,2- difluoroethane (76-12-0)

     

    52

     

     

      1,1,2,2-tetrachloroethane  (79-34-5)

    6.3 x 10-3

     

     

     

      toluene (108-88-3)

     

    4.7

     

    56

      toluene diisocyanate, 2,4- (584-84-9) and 2,6- (91-08-7) isomers

     

    0.0002

     

     

      trichloroethylene (79-01-6)

    5.9 x 10-2

     

     

     

      trichlorofluoromethane  (75-69-4)

     

     

    560

     

      1,1,2-trichloro-1,2,2- trifluoroethane (76-13-1)

     

     

     

    950

      vinyl chloride (75-01-4)

    3.8 x 10-4

     

     

     

      vinylidene chloride (75-35-4)

     

    0.12

     

     

      xylene (1330-20-7)

     

    2.7

     

    65

     

History Note:        Authority G.S. 143-215.3(a)(1); 143-215.107(a)(3),(4),(5); 143B-282;

Eff. May 1, 1990;

Amended Eff. September 1, 1992; March 1, 1992;

Temporary Amendment Eff. July 20, 1997;

Amended Eff. July 7, 2014; May 1, 2014; March 1, 2010; June 1, 2008; April 1, 2005; April 1, 2001; July 1, 1998.